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Matsue, Hideaki
Bunseki, 2002(11), P. 645, 2002/11
no abstracts in English
Kobayashi, Hideo; ; ; ; ; *; *
JNC TN8440 2001-005, 33 Pages, 2001/02
Four mass spectrometers are used for plutonium and uranium isotopic composition analysis in the Plutonium Fuel Center. Analytical errors of the analysis was evaluated based on routine control data obtained with measurement of reference materials. It was confirmed that the errors satisfied the International Target Values for safeguard analysis, and the random error of the analysis was improved by changing conventional method to total evaporation method.
Koide, Kaoru; Nakano, Katsushi; Takeuchi, Shinji; Hama, Katsuhiro; ; Ikeda, Koki;
JNC TN7400 2000-014, 83 Pages, 2000/11
The Japan Nuclear Cycle Development Institute (JNC) has been conducting a wide range of geoscientific research in order to build a firm scientific and technological basis for the research and development of geological disposal. One of the major components of the ongoing geoscientific research programme is the Regional Hydrogeological Study (RHS) project in the Tono region, central Japan. The main goal of the RHS project is to develop and demonstrate surface-based investigation methodologies to characterize geological environments at a regional scale in Japan. The RHS project was initiated in 1992. The first five years of the project were devoted mainly to develop methodologies and techniques for deep borehole investigations in crystalline rock in Japan. Investigations to verify the performance of new instruments and methods for borehole drilling, hydraulic testing and groundwater sampling were conducted. In the last four years, surface-based investigations and a stepwise development of models of the geological environment have been carried out. To date, remote sensing, geological mapping, airborne and ground geophysical investigations, and measurements in eleven deep boreholes have been carried out. Hydro monitorring is continuing in these boreholes. Important results that have been obtained from these investigations include multi-disciplinaly information about the heterogeneity of lithology and hydraulic, geochemical and rock mechanical properties of the granitic rock, and evolution of the groundwater geochemistry. Technical knowledge and experience have been accumulated, which allow application of the methodologies and techniques to characterize the geological environment in crystalline rock. The results from these R%D activities were used as prime inputs for the H12 report that JNC submitted to the Japanese Government in l999. Results from such R&D is also acknowledged by other geoscientific studies in general. JNC will synthesize the results from R&D ...
Osaka, Masahiko; Koyama, Shinichi; Mitsugashira, Toshiaki; Morozumi, Katsufumi; Namekawa, Takashi
JNC TN9400 2000-058, 49 Pages, 2000/04
The analytical technique for Cm contained in a MOX FUEL was developed and analysis of Cm contained in irradiated fuel of experimental fast reactor "JOYO" was carried out, to contribute to evaluation of transmutation characteristics of MA nuclide in the fast reactor. The procedure of ion-exchange separation of Cm with nitric acid-methanol mixed media essential for the isotopic analysis in irradiated MOX fuel was adopted considering for being rapid and easy. The fundamental test to grasp separation characteristics of this procedure, such as Cm elution position and separation capacity between Cm and Am or Eu, was carried out. ln applying this procedure to the analysis of Cm contained in actual specimen, separation condition was evaluated and optimized, and the procedure consist of impurity removal and Am removal process was devised. This procedure resulted in high recovery rate of Cm and high removal rate of Am and impurity which becomes a problem in sample handling and mass-spectrometry such as Eu and Cs. The Cm separation test from irradiated MOX fuel was carried out using this technique, and Cm isotopic ratio analysis was enabled. The analytical technique for Cm contained in irradiated MOX fuel was established using the procedure of ion-exchange separation with nitric acid-methanol mixed media. The analysis of Cm contained in irradiated MOX fuel of experimental fast reactor "Joyo" was carried out. As a result, it was revealed from measured data that Cm content rate was 1.4 4.0lO atom%, small amount of Cm was generated and Cm isotopic ratio was constant above burn-up 60GWd/t.
Yonezawa, Chushiro; Matsue, Hideaki; Adachi, Takeo; Hoshi, Michio; Tachikawa, Enzo*; Povinec, P. P.*; S.W.Fowler*; M.S.Baxter*
IAEA-TECDOC-1094, p.344 - 345, 1999/07
no abstracts in English
Wada, Yukio; Funasaka, Hideyuki; Myochin, Munetaka; Yamamoto, Kazunori; Harada, Hideo; ;
PNC TN8100 96-005, 16 Pages, 1996/01
no abstracts in English
; *; Kurosawa, A.; Kuno, Yusuke; *
PNC TY8605 95-001, 37 Pages, 1995/06
no abstracts in English
Yonezawa, Chushiro; Ito, Yasuo*
Radioisotopes, 43(1), p.50 - 53, 1994/01
no abstracts in English
Yonezawa, Chushiro; Ito, Yasuo*
Isotope News, 0(12), p.2 - 7, 1994/00
no abstracts in English
Yonezawa, Chushiro
Hamon, 3(2), p.5 - 16, 1993/05
no abstracts in English
Bunko Kenkyu, 39(2), p.102 - 109, 1990/00
no abstracts in English
Wakaida, Ikuo; Akaoka, Katsuaki; Miyabe, Masabumi; Khumaeni, A.; Oba, Hironori; Saeki, Morihisa; Ito, Chikara; Otobe, Haruyoshi; Kato, Masaaki
no journal, ,
In the next generation nuclear fuel cycle, low-decontaminated fuel with TRU will be strongly required, and convenience, quick analytical techniques will be necessary. Simultaneous analysis of element and isotope by the combination of Laser Induced Breakdown Spectroscopy (LIBS) and Ablation Resonance Absorption Spectroscopy was demonstrated. For elemental analysis, detection lower limit of 1000 ppm of Pu in U oxide and relative error under 5% have been obtained within 5 min. For isotope analysis, Pu and Pu have been observed completely separated, and detection lower limit of several 10 ppm and error under 1% have been accomplished. A simple antenna coupled microwave assisted LIBS was performed and the enhancement of emission intensity of several 10 times was demonstrated. For liquid sample, ultra-thin laminate flow as the laser focused target was accomplished high sensitivity of ppb. For in-situ monitoring, Optical Fiber LIBS Probe by radiation resistant optical fiber is under construction.
Wakaida, Ikuo; Akaoka, Katsuaki; Miyabe, Masabumi; Kato, Masaaki; Otobe, Haruyoshi; Oba, Hironori; Khumaeni, A.
no journal, ,
In Japan Atomic Energy Agency (JAEA), research and development of quick analysis for next-generation MOX fuel without chemical analysis and neutron measurement had been carried out as the entrusted project by MEXT, and basic performances by using un-irradiated MOX fuel were demonstrated. In elemental analysis by Laser Induced Breakdown Spectroscopy (LIBS) with high resolution spectrometer, relative error of 2.9% at 30% Pu and the detection lower limit of 2,500 ppm in U oxide were demonstrated with the operation time of 5 min.. In isotope ratio analysis by Ablation Resonance Absorption Spectroscopy, tunable semiconductor laser system was constructed, and the relative deviation less than 1% in the ratio of Pu/Pu and sensitivity of 30-100 ppm in U were also accomplished within 5min. operation. As for an analysis in liquid sample, ultra-thin laminate flow was experimented as LIBS target, and the sensitivity comparable to conventional ICP-AES was confirmed.
Miyabe, Masabumi; Oba, Masaki; Akaoka, Katsuaki; Wakaida, Ikuo; Hasegawa, Shuichi*
no journal, ,
no abstracts in English
Shibahara, Yuji*; Fujii, Toshiyuki*; Fukutani, Satoshi*; Takamiya, Koichi*; Hori, Junichi*; Harada, Hideo
no journal, ,
Isotopic analysis of Am-241 and Am-243 samples have been performed using the thermal ionization mass spectrometer TIMS at Research Reactor Institute of Kyoto University. The measurement and analysis results are presented. This research has been performed under the research project entitled as Research and Development for accuracy improvement of neutron nuclear data on minor actinides (AIMAC).
Miyabe, Masabumi; Oba, Masaki; Akaoka, Katsuaki; Wakaida, Ikuo; Hasegawa, Shuichi*
no journal, ,
Because of environmental pollution of the radioactive materials released from TEPCO's Fukushima Daiichi Nuclear Power Station, considerable attention has been focused on food safety in Japan. Whereas the principal pollutants for foods are radioactive Cs and Cs, the radioactive Sr, one of the alkaline earth elements like Ca and its radiation can damage bone marrow, is also one of the most important nuclide considering the possible occurrence of biological concentration through food chain. This Sr is the pure -ray emitter of which energy is 0.546 MeV (28.78 years) and is known as the nuclide for which analysis is difficult. For radiometric analysis, to eliminate various emitters which potentially interfere the Sr analysis, not only a repeated application of ion-exchange and coagulating sedimentation processes but also a period of longer than 2 weeks are needed to establish radioactive equilibrium between Sr and its daughter nuclide Y. To realize a prompt Sr analysis for marine foods, we are developing a new analytical technique by combining resonance ionization spectroscopy (RIS) and ion trap detection. In the present study, we have evaluated ionization efficiency and analytical performances using highly efficient and isotope-selective RIS scheme which we determined in our previous study.